No, skunks urine does not smell when they pee.
It’s a popular misconception that skunks urinate when they spray. That is 100% false.
A skunk’s defensive spray is located in two grape-sized glands to either side of the anal opening and directed through nozzles at the targets.
It is not related in any way to urination or has nothing whatsoever to do with urine. So, a skunk urinating would likely be much the same as most other animals, as far as scent is concerned
ALSO SEE: Do They Use Skunk Spray In Perfume?
Do Skunk Urine Smell?
No, a skunk does not smell bad before it sprays.
Skunks only spray in self-defence so they keep that odour to themselves.